Regular petrol is now high (10%) ethanol E10 petrol with the more expensive premium petrol usually rated at E5 although it is normally closer to E0; that is, a low ethanol content and probably the highest boiling point.
As far as I understand the problem, vapour locks normally occurs in pressurised fuel systems (ie in cars with fuel pumps) due to fuel turning to vapour in fuel lines due to a high temperature affecting the pressure of the delivered fuel.
In this case, it's difficult to see how the formation of vapour in the fuel lines could affect fuel delivery to the carb even if they were getting hot. There's no pump and the system simply relies on gravity.
However, it's possible that the elevated temperature of the carb is causing problems with the atomisation of the fuel that gets sucked into the inlet manifold. It could well weaken the fuel mixture and cause running issues.
I'm pretty sure the carbs don't get particularly hot on the bikes I ride and I'm surprised the Tufnol spacer is not doing a better job. I'd have to check how good an insulator Tufnol is but there may be better choices available.
I would definitely check the petrol tank breather is working properly and also check that the carb float chamber breather hole is operating. If you are using regular petrol, I would recommend changing to slightly more expensive premium or E5 which may ease any problems.