If I understand you correctly, the nipples are not in line with the spokes causing a slight bow? At face value, this would mean that the holes cut in the rim for the nipples are not at the correct angles?
Obviously, you are reliant on the rim supplier to have cut the angles correctly for the front hub you have. You didn't say which type of hub this is but I assume that it is a single sided in which case the spokes on either side are of different lengths?
The classic mistake in rebuilding this type of hub is to get the rim the wrong way round since the nipple hole angles are slightly different for the left and right sets of spokes - that is for the long and short sets of spokes. If the rim has been fitted the correct way round, it is possible to lace up the wheel wrongly but this would take some doing and would be fairly obviously wrong.
If neither of these two possibilities are the case, this would only leave the nipple hole angles not being correct for your hub. If you think this is the case, the first thing I would check is that the rim has been machined for a single sided hub rather than a later full width hub. You have to look very carefully but, for the latter type of hub, the set of nipple angles will be the same on both sides.